An organic Rankine cycle (ORC), is fundamentally the same as a steam Rankine cycle; however, it uses a lower boiling point organic fluid to better match its operation to lower temperature heat sources. ORC systems can achieve better efficiencies than steam turbines for smaller systems (less than a few MW_e).

The Rankine cycle or Rankine Vapor Cycle is the process widely used by power plants such as coal-fired power plants or nuclear reactors. In this mechanism, a fuel is used to produce heat within a boiler, converting water into steam which then expands through a turbine producing useful work.

The Rankine cycle is named after William John Macquorn Rankine, a Scottish polymath professor at Glasgow University. Heat energy is supplied to the system via a boiler where the working fluid (typically water) is converted to a high-pressure gaseous state (steam) in order to turn a turbine.

A real Rankine cycle or non-ideal cycle used in actual power plants do not undergo isentropic compression and expansion by pump and turbine respectively. These processes are irreversible compared to the ideal cycle, and there is an increase in entropy as shown in the T-s diagram below.