The organic Rankine cycle is is similar to the Rankine steam cycle, but uses an organic fluid such as refrigerants and hydrocarbons instead of water as the working fluid. The ordinary Rankine cycle uses thermal power to convert water to steam, which expands through a turbine in order to generate electricity.

The ORC turbogenerator uses medium-to-high-temperature thermal oil to preheat and vaporize a suitable organic working fluid in the evaporator (4>5). The organic fluid vapor rotates the turbine (5>6), which is directly coupled to the electric generator, resulting in clean, reliable electric power.

Additionally, ORCs eliminate the need for full-time plant operators because they operate at lower pressures and do not need water chemistry maintenance. However, working fluid cost, decomposition, temperature limits are an organic Rankine cycle's primary disadvantages.

Refrigerants such as butane, pentane, hexane and silicon oil, which have lower boiling temperatures than water, can be used as working fluids in organic Rankine cycles (ORCs).