The working principle of the organic Rankine cycle is the same as that of the Rankine cycle: the working fluid is pumped to a boiler where it is evaporated, passed through an expansion device (turbine, screw, scroll, or other expander), and then through a condenser heat exchanger where it is finally re-condensed.

The Rankine cycle is an idealized thermodynamic cycle of a heat engine that converts heat into mechanical work while undergoing phase change. The thermal efficiency equals 1 minus the ratio of the low-to-high pressures to the power of 1 minus the reciprocal of the heat capacity ratio.

An organic Rankine cycle (ORC), is fundamentally the same as a steam Rankine cycle; however, it uses a lower boiling point organic fluid to better match its operation to lower temperature heat sources. ORC systems can achieve better efficiencies than steam turbines for smaller systems (less than a few MW_e).

T–s diagram of a typical Rankine cycle operating between pressures of 0.06 bar and 50 bar. Left from the bell-shaped curve is liquid, right from it is gas, and under it is saturated liquid–vapour equilibrium. There are four processes in the Rankine cycle.