An organic Rankine cycle (ORC), is fundamentally the same as a steam Rankine cycle; however, it uses a lower boiling point organic fluid to better match its operation to lower temperature heat sources. ORC systems can achieve better efficiencies than steam turbines for smaller systems (less than a few MW_e).

η=WnetQin=1−QoutQin. The basic Rankine cycle is presented in terms of temperature and entropy change in Figure 10.2. The ideal state of this cycle is reflected in the vertical lines 1-2 and 3-4, when the fluid compressed and expanded. Those processes are shown to proceed isentropically, i.e., without entropy change.

The organic Rankine cycle is is similar to the Rankine steam cycle, but uses an organic fluid such as refrigerants and hydrocarbons instead of water as the working fluid. The ordinary Rankine cycle uses thermal power to convert water to steam, which expands through a turbine in order to generate electricity.

Organic Rankine Cycles differ from traditional steam Rankine Cycles in their use of an organic liquid as opposed to steam as the working fluid. The term ORC is also applied generally to any Rankine cycle with a low-grade heat source.